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Please use this identifier to cite or link to this item: https://libeldoc.bsuir.by/handle/123456789/61971
Title: Band Gap Engineering of Cu2ZnGeS4xSe4(1-x) Solid Solutions
Authors: Khoroshko, V. V.
Pugach, N.
Stanchik, A.
Osmolovskaia, T. N.
Keywords: публикации ученых;crystalline structures;granular materials;electrical conductivity;solar cells
Issue Date: 2025
Publisher: American Chemical Society
Citation: Band Gap Engineering of Cu2ZnGeS4xSe4(1-x) Solid Solutions / V. V. Khoroshko, N. Pugach, A. Stanchik, T. N. Osmolovskaia // The Journal of Physical Chemistry Letters. – 2025. – Vol. 16, iss. 28. – P. 7212–7216.
Abstract: Cu2ZnGeS4xSe4(1–x) (CZGSSe) single crystals were grown by chemical vapor transport (CVT) from synthesized polycrystals using iodine as a transport agent. The elemental analysis showed good agreement with stoichiometry. The values of the band gap of solid solutions are determined from the transmission spectra in the region of the absorption edge, and its concentration dependence, which has a nonlinear quadratic dependence on the composition, is established. These findings highlight the potential of CZGSSe single crystals for optoelectronic applications, emphasizing the tunability of their band gap through composition variation.
URI: https://libeldoc.bsuir.by/handle/123456789/61971
DOI: 10.1021/acs.jpclett.5c01457
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